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HENTEK CAT Catalyst & Catalytic Converter Solutions

Carbon Molecular Sieve – HK-CMS-200 for PSA Nitrogen Generation

Product Overview

Carbon Molecular Sieve (CMS) is a non-polar adsorbent specifically engineered for the separation of nitrogen from air under ambient temperature and pressure swing conditions. HK-CMS-200 is a premium-grade carbon molecular sieve manufactured from high-purity elemental carbon, appearing as black cylindrical pellets with a uniform particle size distribution. The material contains a substantial number of micropores with diameters of approximately 4 angstroms (4Å), which exhibit strong instantaneous affinity for oxygen molecules. This unique pore structure enables CMS to preferentially adsorb oxygen from compressed air, producing a continuous stream of high-purity nitrogen for a wide range of industrial applications.

HK-CMS-200 is the preferred adsorbent for Pressure Swing Adsorption (PSA) nitrogen generation systems, offering high nitrogen production rates, excellent gas recovery efficiency, and long operational life. It is widely recognized as a cost-effective alternative to traditional cryogenic air separation, delivering on-site nitrogen at significantly lower capital and operating costs.

Operating Principle

CMS separates air based on the principle of kinetic selectivity. At equilibrium, the adsorption capacity of CMS for oxygen and nitrogen is relatively similar. However, the diffusion rate of oxygen molecules through the narrow micropores of CMS is substantially faster than that of nitrogen molecules. Under the short adsorption cycle of a PSA process, this difference in diffusion kinetics allows oxygen to be preferentially adsorbed while nitrogen is enriched in the product gas.

The PSA process operates using a continuous two-bed cycle.

Step 1 – Adsorption (Pressurization)

Compressed and purified air flows through the adsorbent bed. Oxygen molecules are selectively adsorbed onto the CMS surface, while nitrogen passes through the bed and is collected as the product gas.

Step 2 – Desorption (Depressurization)

Once the adsorbent approaches oxygen saturation, system pressure is reduced. The adsorbed oxygen is released, regenerating the CMS for the next adsorption cycle.

By alternating between two adsorption beds—one in adsorption while the other regenerates—the PSA system provides a continuous nitrogen supply without external heating, making the process highly energy-efficient and environmentally friendly.

Technical Specifications

Parameter

Specification

Appearance

Black cylindrical pellets

Pellet Diameter

1.1 – 1.8 mm (customizable)

Bulk Density

630 – 700 g/L

Compressive Strength

≥95 – 100 N/pellet

Dust Content

≤100 ppm

Micropore Diameter

4 Å

Adsorption Cycle Time

120 seconds

Storage Life

>3 years (sealed, dry conditions)

Performance Data (at 0.8 MPa Adsorption Pressure)

Nitrogen Purity (%)

Nitrogen Production (NM³/h·t)

Nitrogen/Air Ratio (%)

99.99

70 – 75

≥21

99.9

125 – 140

≥27

99.5

200

≥36

99.0

240 – 260

≥41

98.0

325 – 330

≥48

97.0

365

≥48

Note: Performance varies with operating conditions. HK-CMS-200 achieves 200 NM³/h·t at 99.5% nitrogen purity under standard operating conditions.

Core Advantages

High Nitrogen Production Efficiency

HK-CMS-200 delivers excellent nitrogen output across a wide purity range. At 99.5% nitrogen purity, it produces approximately 200 NM³ of nitrogen per metric ton of CMS per hour. Even at 99.99% purity, it maintains a production rate of 70–75 NM³/h·t, making it suitable for demanding industrial applications.

Low Pressure Drop and Energy Consumption

The optimized pellet size and bulk density (630–700 g/L) minimize airflow resistance, reducing compressor power consumption and lowering overall operating costs.

High Mechanical Strength

With compressive strength exceeding 95–100 N per pellet, HK-CMS-200 resists crushing and attrition throughout repeated PSA pressure cycles. Extremely low dust content (≤100 ppm) helps maintain clean adsorbent beds and prolongs system life.

Long Service Life

Under normal operating conditions, HK-CMS-200 typically provides a service life of 5–8 years, maintaining stable adsorption performance through thousands of adsorption-desorption cycles.

Stable Performance

Each production batch undergoes strict quality control to ensure consistent particle size, bulk density, and adsorption characteristics. HK-CMS-200 can directly replace many

On-Site Nitrogen Generation

HK-CMS-200 eliminates dependence on high-pressure gas cylinders or liquid nitrogen deliveries. Nitrogen purity and flow can be adjusted to meet process requirements, and optional purification systems can reduce oxygen levels below 5 ppm with dew points below −60°C.

Applications

HK-CMS-200 carbon molecular sieve is widely used in PSA nitrogen generation systems across numerous industries.

Industry

Typical Applications

Petrochemical & Oil & Gas

Tank blanketing, pipeline purging, pressure maintenance, enhanced oil recovery, inerting

Metal Heat Treatment

Controlled atmosphere annealing, carburizing, sintering, brazing, bright heat treatment

Electronics & Semiconductor

Inert atmosphere for electronic component manufacturing, soldering, wave soldering, semiconductor processing

Food & Beverage

Modified atmosphere packaging (MAP), food preservation, beverage bottling, inert gas blanketing

Pharmaceutical

Inert gas protection during synthesis, packaging, storage, and production

Coal Industry

Fire prevention, mine inerting, goaf inertization

Cable & Wire Manufacturing

Nitrogen curing for cross-linked polyethylene (XLPE) cable production

Packaging and Storage

Packaging Options

Packaging Type

Specification

Plastic Drum

20 kg

Plastic Drum

25 kg

Plastic Drum

40 kg

Custom Packaging

Available upon request

Storage Information

Item

Specification

Minimum Order Quantity (MOQ)

20 kg

Shelf Life

More than 3 years in original unopened packaging

Storage Conditions

Store in sealed containers in a cool, dry, well-ventilated area. Protect from moisture, direct sunlight, and ignition sources. Do not open packaging until ready for use to prevent premature adsorption of moisture and contaminants.

Technical Support

HENTEKCAT provides comprehensive technical support, including:

  • Product selection and grade recommendations based on nitrogen purity and flow rate requirements.
  • PSA system design and adsorbent bed sizing assistance.
  • Loading, commissioning, and startup guidance.
  • Process optimization for maximum nitrogen generation efficiency.
  • Troubleshooting, diagnostics, and performance evaluation.

HENTEKCAT – Adsorption Technologies, Engineered for Performance.